Combine flour, sugars, cocoa, baking soda, baking powder, and salt into the bowl of a mixer. Mix on low. Add eggs, buttermilk, coffee, oil, and vanilla. Beat on medium speed until smooth and completely combined.
2 cups (8.5 oz) all-purpose flour, 1 cup (7 oz) granulated sugar, 1 cup (7 oz) brown sugar, 1 cups (3 oz) unsweetened cocoa powder, 2 teaspoons baking soda, 1 teaspoon baking powder, 1 teaspoon salt, 2 large eggs, 1 cup buttermilk, 1 cup warm brewed coffee, ⅓ cup plus 1 tablespoon vegetable oil, 2 teaspoons vanilla extract